| Hydrogen
From Wikipedia, the free encyclopedia
This article is about the chemistry of hydrogen. For the physics of atomic hydrogen, see Hydrogen atom. For other meanings, see Hydrogen (disambiguation).
1
(none) ? hydrogen ’ helium
-
‘
H
“
Li

Periodic table - Extended periodic table
General
Name, symbol, number
hydrogen, H, 1
Chemical series
nonmetals
Group, period, block
1, 1, s
Appearance
colorless
Standard atomic weight
1.00794(7) g·mol1
Electron configuration
1s1
Electrons per shell
1
Physical properties
Phase
gas
Density
(0 °C, 101.325 kPa)
0.08988 g/L
Melting point
14.01 K
(259.14 °C, 434.45 °F)
Boiling point
20.28 K
(252.87 °C, 423.17 °F)
Triple point
13.8033 K (-259°C), 7.042 kPa
Critical point
32.97 K, 1.293 MPa
Heat of fusion
(H2) 0.117 kJ·mol1
Heat of vaporization
(H2) 0.904 kJ·mol1
Specific heat capacity
(25 °C) (H2)
28.836 J·mol1·K1
Vapor pressure
P/Pa
1
10
100
1 k
10 k
100 k
at T/K
15
20
Atomic properties
Crystal structure
hexagonal
Oxidation states
1, 1
(amphoteric oxide)
Electronegativity
2.20 (Pauling scale)
Ionization energies
1st: 1312.0 kJ·mol1
Atomic radius
25 pm
Atomic radius (calc.)
53 pm
Covalent radius
37 pm
Van der Waals radius
120 pm
Miscellaneous
Thermal conductivity
(300 K) 180.5 m W·m1·K1
Speed of sound
(gas, 27 °C) 1310 m/s
CAS registry number
1333-74-0
Selected isotopes
Main article: Isotopes of hydrogen
iso
NA
half-life
DM
DE (MeV)
DP
1H
99.985%
1H is stable with 0 neutrons
2H
0.015%
2H is stable with 1 neutron
3H
trace
12.32 y
²
0.019
3He
References
This box: view " talk " edit
Hydrogen (pronounced /ÈhajdrYd’Yn/[1]) is the chemical element with atomic number 1. It is represented by the symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly flammable diatomic gas with the molecular formula H2. With an atomic mass of 1.00794 amu, hydrogen is the lightest element.
Hydrogen is the most abundant of the chemical elements, constituting roughly 75% of the universe's elemental mass.[2] Stars in the main sequence are mainly composed of hydrogen in its plasma state. Elemental hydrogen is relatively rare on Earth, and is industrially produced from hydrocarbons such as methane, after which most elemental hydrogen is used "captively" (meaning locally at the production site), with the largest markets about equally divided between fossil fuel upgrading (e.g., hydrocracking) and ammonia production (mostly for the fertilizer market). Hydrogen may be produced from water using the process of electrolysis, but this process is presently significantly more expensive commercially than hydrogen production from natural gas.[3]
The most common naturally occurring isotope of hydrogen, known as protium, has a single proton and no neutrons. In ionic compounds it can take on either a positive charge (becoming a cation composed of a bare proton) or a negative charge (becoming an anion known as a hydride). Hydrogen can form compounds with most elements and is present in water and most organic compounds. It plays a particularly important role in acid-base chemistry, in which many reactions involve the exchange of protons between soluble molecules. As the only neutral atom for which the Schrödinger equation can be solved analytically, study of the energetics and bonding of the hydrogen atom has played a key role in the development of quantum mechanics.
The solubility and characteristics of hydrogen with various metals are very important in metallurgy (as many metals can suffer hydrogen embrittlement[4]) and in developing safe ways to store it for use as a fuel.[5] Hydrogen is highly soluble in many compounds composed of rare earth metals and transition metals[6] and can be dissolved in both crystalline and amorphous metals.[7] Hydrogen solubility in metals is influenced by local distortions or impurities in the metal crystal lattice.[8]
|